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Beilstein J. Org. Chem. 2013, 9, 852–859, doi:10.3762/bjoc.9.98
Graphical Abstract
Scheme 1: Aza-Darzens synthesis of an N-Dpp vinyl aziridine.
Scheme 2: Closed transition state delivers E-aziridines.
Scheme 3: Open transition state leading to (Z)-5.
Scheme 4: Ring opening by Grignard reagent.